全文获取类型
收费全文 | 39214篇 |
免费 | 3504篇 |
国内免费 | 2164篇 |
专业分类
化学 | 20469篇 |
晶体学 | 208篇 |
力学 | 1263篇 |
综合类 | 749篇 |
数学 | 10685篇 |
物理学 | 11508篇 |
出版年
2023年 | 274篇 |
2022年 | 453篇 |
2021年 | 1382篇 |
2020年 | 870篇 |
2019年 | 1014篇 |
2018年 | 762篇 |
2017年 | 867篇 |
2016年 | 1064篇 |
2015年 | 1072篇 |
2014年 | 1404篇 |
2013年 | 2569篇 |
2012年 | 1668篇 |
2011年 | 1883篇 |
2010年 | 1767篇 |
2009年 | 2189篇 |
2008年 | 2365篇 |
2007年 | 2438篇 |
2006年 | 1888篇 |
2005年 | 1273篇 |
2004年 | 1152篇 |
2003年 | 1262篇 |
2002年 | 3727篇 |
2001年 | 1123篇 |
2000年 | 813篇 |
1999年 | 670篇 |
1998年 | 616篇 |
1997年 | 507篇 |
1996年 | 539篇 |
1995年 | 482篇 |
1994年 | 469篇 |
1993年 | 489篇 |
1992年 | 484篇 |
1991年 | 329篇 |
1990年 | 276篇 |
1989年 | 231篇 |
1988年 | 248篇 |
1987年 | 217篇 |
1986年 | 229篇 |
1985年 | 353篇 |
1984年 | 252篇 |
1983年 | 155篇 |
1982年 | 311篇 |
1981年 | 485篇 |
1980年 | 432篇 |
1979年 | 473篇 |
1978年 | 380篇 |
1977年 | 291篇 |
1976年 | 248篇 |
1974年 | 80篇 |
1973年 | 155篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
Suppose that is a one-dimensional Brownian motion with negative drift . It is possible to make sense of conditioning this process to be in the state 0 at an independent exponential random time and if we kill the conditioned process at the exponential time the resulting process is Markov. If we let the rate parameter of the random time go to 0, then the limit of the killed Markov process evolves like conditioned to hit 0, after which time it behaves as killed at the last time visits 0. Equivalently, the limit process has the dynamics of the killed “bang–bang” Brownian motion that evolves like Brownian motion with positive drift when it is negative, like Brownian motion with negative drift when it is positive, and is killed according to the local time spent at 0.An extension of this result holds in great generality for a Borel right process conditioned to be in some state at an exponential random time, at which time it is killed. Our proofs involve understanding the Campbell measures associated with local times, the use of excursion theory, and the development of a suitable analogue of the “bang–bang” construction for a general Markov process.As examples, we consider the special case when the transient Borel right process is a one-dimensional diffusion. Characterizing the limiting conditioned and killed process via its infinitesimal generator leads to an investigation of the -transforms of transient one-dimensional diffusion processes that goes beyond what is known and is of independent interest. 相似文献
102.
A simple, sensitive and rapid ultra‐high‐performance liquid chromatography–electrospray ionization–tandem mass spectrometry method was developed and validated for the quantification of warfarin and 7‐hydroxy warfarin in Sprague Dawley (SD) rats. Animals were administered a single dose of warfarin sodium formulations (crystalline and amorphous) at 12 mg/kg via oral gavage and blood was drawn over a 96‐h time course. Sample process recoveries, matrix effect and analyte stability were determined. The linearity for warfarin and 7‐hydroxy warfarin was from 5 to 2000 ng/mL in blank SD rat plasma. Correlation coefficients (r2) for standard calibration curves were >.98 and analytes quantified within ±15% of target at all calibrator concentrations. The average percent accuracy and precision for intra‐ and inter‐day were 93.7%–113.8% and ≤12.1%, respectively, for warfarin and 7‐hydroxy warfarin, across the quality control standards (5, 10, 500, 1800 and 2000 ng/mL). Acceptable analytical recovery (>55%) was achieved with process efficiencies >41.5% and matrix effects <139.9% over the analytical range. Both analytes were stable in stock solution, autosampler, benchtop and three cycles of freeze–thaw with percent accuracy ≥90.2% and precision (percent relative standard deviation) ≤14%. The validated method was successfully applied to a pre‐clinical bioavailability study of crystalline and amorphous warfarin sodium formulations in SD rats. 相似文献
103.
Jinghua YANG 《数学年刊B辑(英文版)》2019,40(2):227-236
In this paper, the author gives the discrete criteria and J\o
rgensen inequalities of subgroups for the special linear group on
$\overline{\mathrm{F}}((t))$ in two and higher dimensions. 相似文献
104.
105.
106.
Ivor Cribben 《商业与工业应用随机模型》2019,35(2):299-320
We propose two robust data‐driven techniques for detecting network structure change points between heavy‐tailed multivariate time series for situations where both the placement and number of change points are unknown. The first technique utilizes the graphical lasso method to estimate the change points, whereas the second technique utilizes the tlasso method. The techniques not only locate the change points but also estimate an undirected graph (or precision matrix) representing the relationship between the time series within each interval created by pairs of adjacent change points. An inference procedure on the edges is used in the graphs to effectively remove false‐positive edges, which are caused by the data deviating from normality. The techniques are compared using simulated multivariate t‐distributed (heavy‐tailed) time series data and the best method is applied to two financial returns data sets of stocks and indices. The results illustrate the method's ability to determine how the dependence structure of the returns changes over time. This information could potentially be used as a tool for portfolio optimization. 相似文献
107.
108.
Dr. Lingxing Zeng Biyu Kang Fenqiang Luo Yixing Fang Cheng Zheng Junbin Liu Renpin Liu Xinye Li Prof. Dr. Qinghua Chen Prof. Dr. Mingdeng Wei Prof. Dr. Qingrong Qian 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(58):13411-13421
Sodium/potassium-ion batteries (SIBs/PIBs) arouse intensive interest on account of the natural abundance of sodium/potassium resources, the competitive cost and appropriate redox potential. Nevertheless, the huge challenge for SIBs/PIBs lies in the scarcity of an anode material with high capacity and stable structure, which are capable of accommodating large-size ions during cycling. Furthermore, using sustainable natural biomass to fabricate electrodes for energy storage applications is a hot topic. Herein, an ultra-small few-layer nanostructured MoSe2 embedded on N, P co-doped bio-carbon is reported, which is synthesized by using chlorella as the adsorbent and precursor. As a consequence, the MoSe2/NP-C-2 composite represents exceedingly impressive electrochemical performance for both sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs). It displays a promising reversible capacity (523 mAh g−1 at 100 mA g−1 after 100 cycles) and impressive long-term cycling performance (192 mAh g−1 at 5 A g−1 even after 1000 cycles) in SIBs, which are some of the best properties of MoSe2-based anode materials for SIBs to date. To further probe the great potential applications, full SIBs pairing the MoSe2/NP-C-2 composite anode with a Na3V2(PO4)3 cathode also exhibits a satisfactory capacity of 215 mAh g−1 at 500 mA g−1 after 100 cycles. Moreover, it also delivers a decent reversible capacity of 131 mAh g−1 at 1 A g−1 even after 250 cycles for PIBs. 相似文献
109.
A linear optical unambiguous discrimination of hyperentangled Bell states is proposed for two‐photon systems entangled in both the polarization and momentum degrees of freedom (DOFs) assisted by time bin. This unambiguous discrimination scheme can completely identify 16 orthogonal hyperentangled Bell states using only linear optical elements, where the function of the auxiliary entangled Bell state is replaced by time bin. Moreover, the possibility of extending this scheme for distinguishing hyperentangled Bell states in n DOFs is discussed, and it shows that hyperentangled Bell states in n ( ) DOFs can be distinguished with k ( ) auxiliary entangled states of additional DOFs by introducing a time delay, which decreases the auxiliary entanglement resource required for unambiguous discrimination of hyperentangled Bell state. Therefore, this scheme provides a new way for distinguishing hyperentangled states with current technology, which will extend the application of discrimination of hyperentangled states via linear optics to other quantum information protocols besides hyperdense coding schemes in the future. 相似文献
110.
Jiankun Shao Rishav Choudhary David F. Davidson Ronald K. Hanson Samuel Barak Subith Vasu 《Proceedings of the Combustion Institute》2019,37(4):4555-4562
The need for more efficient power cycles has attracted interest in super-critical CO2 (sCO2) cycles. However, the effects of high CO2 dilution on auto-ignition at extremely high pressures has not been studied in depth. As part of the effort to understand oxy-fuel combustion with massive CO2 dilution, we have measured shock tube ignition delay times (IDT) for methane/O2/CO2 mixtures and hydrogen/O2/CO2 mixtures using sidewall pressure and OH* emission near 306?nm. Ignition delay time was measured in two different facilities behind reflected shock waves over a range of temperatures, 1045–1578?K, in different pressures and mixture regimes, i.e., CH4/O2/CO2 mixtures at 27–286 atm and H2/O2/CO2 mixtures at 37–311 atm. The measured data were compared with the predictions of two recent kinetics models. Fair agreement was found between model and experiment over most of the operating conditions studied. For those conditions where kinetic models fail, the current ignition delay time measurements provide useful target data for development and validation of the mechanisms. 相似文献